Bulletin of the Chemical Society of Japan

Photo-induced Friedel-Crafts acylation of anthracene with aroyl chlorides.

T Tamaki

Index: Tamaki,T. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, # 4 p. 1145 - 1152

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Citation Number: 11

Abstract

The photo-excitation of anthracene (1) in the presence of benzoyl chloride and its p-or m- substituted compounds (2) gave the corresponding 2-and 9-aroylanthracenes. No isomeric 1-aroylanthracenes (3) were detected. The aroyl chlorides (2) were found to quench the fluorescence of 1. The quenching constants obtained increased with increasing electron- withdrawing ability of the substituents and are in agreement with those independently ...