Bulletin of the Chemical Society of Japan

The reaction of cycloalkanones with copper (II) halides. II. The reaction of cyclohexanones with copper (II) bromide

K Nishizawa, JY Satoh

Index: Nishizawa,K.; Satoh,J.Y. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 1875 - 1877

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Citation Number: 5

Abstract

The reaction of cyclohexanones with copper (II) bromide gave polybrominated cyclohexanediones in all cases except for the case of 3, 5-dimethylcyclohexanone. Moreover, in this reaction, a pyrocatechol and a phenol derivative were obtained from 4- methyl-and 3, 5-dimethylcyclohexanone respectively. The mechanism of this reaction was discussed.