Monomeric (dialkylamino) boranes: a new and efficient boron source in palladium catalyzed C–B bond formation with aryl halides

L Euzenat, D Horhant, Y Ribourdouille…

Index: Euzenat, Lisenn; Horhant, David; Ribourdouille, Yann; Duriez, Christophe; Alcaraz, Gilles; Vaultier, Michel Chemical Communications, 2003 , # 18 p. 2280 - 2281

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Citation Number: 32

Abstract

Thermal decomposition of hindered amine-borane adducts leads in high yields to monomeric (dialkylamino) boranes R1R2N–BH2 (R1 and R2= alkyl) that are new and efficient boron-sources in the Pd0 catalyzed borylation reaction affording monomeric aryl (dialkylamino) boranes R1R2N–BHR3 (R3= aryl).