Synthesis of building blocks for the development of the SUPRAPhos ligand library and examples of their application in catalysis

…, R Lemmens, PWNM Van Leeuwen…

Index: Goudriaan, P. Elsbeth; Jang, Xiao-Bin; Kuil, Mark; Lemmens, Renske; Van Leeuwen, Piet W. N. M.; Reek, Joost N. H. European Journal of Organic Chemistry, 2008 , # 36 p. 6079 - 6092

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Citation Number: 23

Abstract

Abstract We have previously introduced the SUPRAPhos ligand library, which is based on components that are self-assembled through nitrogen–zinc interactions, and report here an extension of this library, which widens the scope for application in asymmetric homogeneous catalysis. For example, we report the synthesis of phosphorus amidite appended porphyrins and building blocks with stereogenic centers at the phosphorus. ...