Russian Journal of Organic Chemistry

Hydrogen peroxide-or sodium hypochlorite-induced bromination of 1-arylbut-2-enes

OA Sadygov, KM Alimardanov

Index: Sadygov; Alimardanov Russian Journal of Organic Chemistry, 2007 , vol. 43, # 11 p. 1661 - 1670

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Citation Number: 3

Abstract

Abstract Bromination of 1-arylbut-2-enes in the system [HBr or NaBr (KBr)-HX]-H 2 O 2 (or NaOCl) under relatively mild conditions leads to electrophilic addition of bromine or hypobromous acid at the side-chain double bond. Under more severe conditions, the process is accompanied by bromination of the aromatic ring. Treatment of the title compounds with peroxy acids (RCOOH-H 2 O 2) gives the corresponding epoxy ...