Chemistry Letters

NEW SYNTHESIS OF METHYL 2-TRIORGANOSILYL-3-BUTENOATES AS A NEW SYNTHON OF 3-METHOXYCARBONYLALLYL ANION

Y Naruta, H Uno, K Maruyama

Index: Naruta, Yoshinori; Uno, Hidemitsu; Maruyama, Kazuhiro Chemistry Letters, 1982 , p. 961 - 964

Full Text: HTML

Citation Number: 12

Abstract

Methyl 2-triorganosilyl-3-butenoates, which are selectively obtained from the carboxylation of the corresponding allylsilanes via allylic aluminates, react with various kinds of electrophiles to give γ substituted (E)-α, β-unsaturated esters in highly regio and stereoselective manner with the aid of a Lewis acid.