Tetrahedron letters

Stereospecific phenylation of alkenylsilanes with phenylpalladium acetate

K Kikukawa, K Ikenaga, F Wada, T Matsuda

Index: Kikukawa, Kiyoshi; Ikenaga, Kazutoshi; Wada, Fumio; Matsuda, Tsutomu Tetrahedron Letters, 1984 , vol. 25, # 50 p. 5789 - 5792

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Citation Number: 21

Abstract

(E)- and (Z)-RCH=CHSiMe 3 (R=Ph, nC 6 H 13 , CH 3 OCH 2 ) reacted stereospecifically with Ph-Pd-OAc to give RCH=C(Ph)SiMe 3 and R(Ph)C=CHSiMe 3 with inversion of the starting geometry with respect to R and Me 3 Si groups. ... K. Kikukawa, M. Naritomi, GX. He, F. Wada, and T. Matsuda, submitted to J. Org. Chem. ... Matoba K. , Motofusa S.-I. , Sik Cho C. , Ohe K. , Uemura S.