Towards co-operative reactivity in conjoint classical-organometallic heterometallic complexes: the co-ordination chemistry of novel ligands with triphenylphosphine …

SE Watkins, DC Craig, SB Colbran

Index: Watkins, Scott E.; Craig, Donald C.; Colbran, Stephen B. Journal of the Chemical Society, Dalton Transactions, 2002 , # 12 p. 2423 - 2436

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Abstract

With a view towards later studies of co-operativity in heteronuclear complexes with hard classical (oxygen-activating) and soft organometallic (organic-substrate binding) metal centres, four novel ditopic N3P-donor ligands (L1–L4), each comprising triphenylphosphine tethered to an N, N′-bis (2-pyridyl-2-ethyl) amine (bpea) or a 1, 4-diisopropyl-1, 4, 7- triazacyclononane (tacn*) N3-donor group, have been designed and prepared by ...