Construction of 2, 3-and 3, 4-Functionalized Silacyclopentanes: Synthesis of 6-Aza-2, 2-Diphenyl-2-Silabicyclo [3.1. 0] Hexane and 6-Aza-3, 3-Diphenyl-3-Silabicyclo [ …

…, M Barreau, D Damour, A Renaudon…

Index: Mignani, Serge; Barreau, Michel; Damour, Dominique; Renaudon, Alain; Dejean, Valerie; Manuel, Georges Synthetic Communications, 1998 , vol. 28, # 7 p. 1163 - 1173

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Citation Number: 7

Abstract

Abstract: The synthesis of five azasilabicycl0[3.1 .O]hexanes containing an aziridine function in the a- or the p- position of the silicon atom is described. These bicyclic heterocompounds differ by the various substituents (H, Me, CO2Et, CPh3) on the nitrogen atom. ... The high versatility and reactivity of aziridines make them very useful electrophilic reagents for the synthesis of organic polyfimctionalized derivatives: for example, ring opening reactions lead generally to fruns ...