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Metal–organic gels as functionalisable supports for catalysis
…, X Wang, L He, L Chen, CY Su, SL James
Index: Zhang, Jianyong; Wang, Xiaobing; He, Lisi; Chen, Liuping; Su, Cheng-Yong; James, Stuart L. New Journal of Chemistry, 2009 , vol. 33, # 5 p. 1070 - 1075
Modification of Fe-tricarboxylate based metal–organic gels yielded tert-butyl substituted or phosphine-functionalised gels in alcohols or DMF, which were prepared from 5-tert- butylisophthalic acid and 5-diphenylphosphanylisophthalic acid, respectively. Owing to their permeability, such phosphine-functionalised metal–organic gels can act as a new type of functionalisable porous scaffold. The phosphorus-containing gel was subsequently ...