Tetrahedron letters

σ-Assistance of the C 4 C 7 bond in the solvolysis of 1-norbornyl triflates

…, MER Herrero, MI de Dios, ET Vilar, LR Subramanian

Index: Martinez; Garcia Martinez; Barcina; Osio Barcina; Herrero; Rodriguez Herrero; De Dios; Iglesias De Dios; Vilar; Teso Vilar; Subramanian Tetrahedron Letters, 1994 , vol. 35, # 11 p. 1793 - 1796

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Citation Number: 5

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The solvolysis of 4,7,7-trimethyl-1-norbornyl triflate (5) proceeds under σ-participation of the C 4 C 7 bond, with formation of the σ bridged cation 22 as intermediate. ... The solvolysis of 4,7,7-trimethyl-1-norbornyl triflate proceeds under σ-participation of the C 4 C 7 bond, ...