Tetrahedron

Synthesis of 3-aryl-4-methyl-1, 2-benzenedisulfonimides, new chiral Brønsted acids. A combined experimental and theoretical study

M Barbero, S Bazzi, S Cadamuro, L Di Bari, S Dughera…

Index: Barbero, Margherita; Bazzi, Stefano; Cadamuro, Silvano; Di Bari, Lorenzo; Dughera, Stefano; Ghigo, Giovanni; Padula, Daniele; Tabasso, Silvia Tetrahedron, 2011 , vol. 67, # 32 p. 5789 - 5797

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Citation Number: 6

Abstract

Abstract We have recently reported the use, in catalytic amounts, of 1, 2- benzenedisulfonimide as a safe Brønsted acid in some acid-catalyzed organic reactions. With the design of new and chiral acid organocatalysts with the structure of 1, 2- benzenedisulfonimide in mind, we herein propose a synthesis of 1, 2-benzenedisulfonimide derivatives bearing an aryl group in the 3-position with good overall yields. The chirality of ...