The Journal of Physical Chemistry

Disproportionation to combination ratios of alkoxy radicals with nitric oxide

P Morabito, J Heicklen

Index: Morabito, Paul; Heicklen, Julian Journal of Physical Chemistry, 1985 , vol. 89, # 13 p. 2914 - 2916

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Citation Number: 16

Abstract

The disproportionation to combination ratios were measured at 175 OC for the reactions RO+ l5NO-ROI5NO (2a) and RO+ I5NO-RCHO+ H15N0 (2b), with the following alkoxy radicals: C2H50, n-C3H70,? &&go, and i-C4H90. The alkoxy radical was generated by the thermal decomposition of the corresponding alkyl nitrite in the presence of I5NO. The rate of the corresponding isotopically enriched alkyl nitiite was measured by mass spectrometry ...

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