Bulletin of the Chemical Society of Japan

Preparation and Structural Characterization of Bis [tris (trimethylsilyl) germyl] zinc,[(Me3Si) 3Ge] 2Zn

M Nanjo, T Oda, K Mochida

Index: Nanjo, Masato; Oda, Takashi; Mochida, Kunio Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 6 p. 1261 - 1264

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Citation Number: 5

Abstract

Bis [tris (trimethylsilyl) germyl] zinc,[(Me 3 Si) 3 Ge] 2 Zn, was prepared by the reaction of [tris (trimethylsilyl) germyl] lithium,(Me 3 Si) 3 GeLi (thf), with zinc chloride, ZnCl 2, and by the reaction of tris (trimethylsilyl) germane,(Me 3 Si) 3 GeH, with diethylzinc, Et 2 Zn. The molecular structure of [(Me 3 Si) 3 Ge] 2 Zn was determined by spectroscopic and X-ray diffraction methods. In [(Me 3 Si) 3 Ge] 2 Zn, the two tris (trimethylsilyl) germyl ligands,(Me ...