Some unusual oxidation products of 2, 6-di-tert-butyl-4-methylphenol

BM Benjamin, VF Raaen, EW Hagaman…

Index: Benjamin,B.M. et al. Journal of Organic Chemistry, 1978 , vol. 43, # 15 p. 2986 - 2991

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Citation Number: 21

Abstract

The potassium permanganate oxidation of 2, 6-di-tert-butyl-4-methylphenol(l), adsorbed on a stationary Celite phase, gives several interesting monomeric products in low yields. These products were identified primarily by 13C and 1H NMR. The products of oxidation of 1 with performic acid and also with oxygen in alkaline ethanol are related and their structures and NMR spectral features are also discussed.