Kinetics and mechanism of the interaction of amines with aryl β??haloethyl sulphones

VN Matvienko, IF Perepichka, AF Popov…

Index: Matvienko, Viktor N.; Perepichka, Igor F.; Popov, Anatoly F.; Piskunova, Zhanna P. Journal of Physical Organic Chemistry, 1994 , vol. 7, # 10 p. 525 - 533

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Abstract

Abstract The influence of a number of factors, ie amine basicity, substrate structure, temperature and deuterium isotope effect, on the rate of phenyl β-bromoethyl sulphone and aryl β-chloroethyl sulphone 1, 2-elimination by reaction with amines in acetonitrile was investigated. On the basis of a comparative analysis of the ρ 0, β, k H/k D, ΔH‡ and ΔS math image values obtained with those for the reaction of β-halopropiophenone 1, 2-elimination ...