Abstract: This paper describes several new stereospecific reactions at chiral sulfur, and completion of the first known stereochemical reaction cycle in which only a single ligand is common to all compounds of the reaction cycle (monoligostatic). Additional diligostatic and triligostatic stereochemical reaction cycles are described that involve sulfoxides, sulfimides, sulfoximides, sulfinamides, sulfinamidines, sulfinate, and sulfinimidate esters (compounds ...
