Competing electron transfer proton abstraction and nucleophilic substitutions in gas-phase reactions of (radical) anions with chloro-and bromomethanes.

…, G Groothuis, S Ingemann Jorgensen…

Index: Staneke; Groothuis; Ingemann; Nibbering Journal of Physical Organic Chemistry, 1996 , vol. 9, # 7 p. 471 - 486

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Citation Number: 21

Abstract

The transfer of a single electron has become recognized as a central step in many organic reactions described commonly as two electron centered processes.'In particular, the role of single electron transfer (SET) in organic processes has been studied extensively since the pioneering work of Komblum, Russell and Bunnett concerning nucleophilic aromatic substitutions proceeding by a pathway which is now known as the The experimental ...