Synthetic Communications

Studies on the Syntheses of Multilayered [2. 2] Paracyclophanes

T Otsubo, H Horita, S Misumi

Index: Otsubo,T. et al. Synthetic Communications, 1976 , vol. 6, p. 591 - 596

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Citation Number: 26

Abstract

Abstract It is well-known that a number of double-layered compounds such as [2. 2] paracyclophane show anomalous physical and chemical properties due to the transannular π-electronic interaction between the stacked aromatic rings. 2) Moreover, the interaction significantly increases with an increase of the layers as observed in a series of multilayered [2. 2] paracyclophanes3) and thereby it is of great interest to search a possibility of an ...