Bimanes. 23. The synthesis and properties of vinyl-9, 10-dioxabimanes

…, M Baud'huin, D Marciano, I Goldberg

Index: Kosower, Edward M.; Zbaida, David; Baud'huin, Michel; Marciano, Daniele; Goldberg, Israel Journal of the American Chemical Society, 1990 , vol. 112, # 20 p. 7305 - 7314

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Citation Number: 7

Abstract

Abstract: Syntheses and useful reactions of syn-vinylbimanes are reported. The precursors are syn-(ethy1, methyl) bimane (4, 6-diethyI-3, 7-dimethyl-l, 5-diazabicyclo [3.3. 0] octa-3, 6- diene-2, 8dione)(syn-(CH3CH2, CH3) B)(2) and syn-(ethy1, chloro) bimane (4, 6-diethyl-3, 7- dichloro-1, fi-diazabicyclo [3.3. O] octa-3, 6-diene-2, 8-dione)(syn-(CH3CH2, C1) B)(4). Bromination of 2 yields the 1-bromoethyl derivative (syn-(CH3CHBr, CH3)(CH3CH2, CH3) ...