The reactions of the singlet NH radicals with C4 olefins in the liquid phase.

J Hamada, S Tsunashima, S Sato

Index: Hamada, Jun-ichi; Tsunashima, Shigeru; Sato, Shin Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 3 p. 662 - 666

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Citation Number: 6

Abstract

The reactions of NH radicals with C 4 olefins, trans-and cis-2-butenes, 1-butene, and isobutene, were investigated by the photolysis of hydrogen azide in the liquid olefin at 0° C and at the temperature of Dry Ice–methanol. Except for nitrogen and ammonia, amines and aziridines were found to be formed in good yield. 2-Butene-1-amine and trans-2, 3- dimethylaziridine from trans-2-butene, 2-butene-1-amine and cis-2, 3-dimethylaziridine ...