Electronic and Molecular Structure of Simple 3, 3′??Bicyclopropenyls. Photoelectron Spectroscopy and Model Calculations

J Spanget??Larsen, C De Korswagen…

Index: Spanget-Larsen, Jens; Korswagen, Carla de; Eckert-Maksic, Mirjana; Gleiter, Rolf Helvetica Chimica Acta, 1982 , vol. 65, # 3 p. 968 - 982

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Citation Number: 19

Abstract

Abstract The electronic and molecular structure of 3, 3′-bicyclopropenyl (1) and its alkyl derivatives 3, 3′-dirnethyl-3, 3′-bicyclopropenyl (2), dispiro [2.0. 2.3] nona-1, 5-diene (3), dispiro [2.0. 2.4] deca-1, 5-diene (4), dispiro [2.0. 2.5] undeca-1, 5-diene (5), and dispiro [2.0. 2.6] dodeca-1, 5-diene (6) are studied by means of photoelectron spectroscopy and model calculations. Through-bond'effects in model compound 1 are analyzed in detail, ...