Alkyne metathesis with simple catalyst systems: poly (p-phenyleneethynylene) s

L Kloppenburg, D Song, UHF Bunz

Index: Kloppenburg; Song; Bunz Journal of the American Chemical Society, 1998 , vol. 120, # 31 p. 7973 - 7974

Full Text: HTML

Citation Number: 141

Abstract

Alkene metathesis is now an established and powerful tool for organic, bioorganic, 2 and polymer synthesis. 3, 4 The conceptually related process of alkyne metathesis, however, has found much less attention. Metathesis of CC triple bonds by molybdenum/phenol species has been known since the 1970s5 but was never developed into an established synthetic method. A recent report describes the metathesis of internal alkynes at elevated ...