Selective Hydroformylation of Internal Acetylenes by PdCl2 (PCy3) 2: Remarkable Synergistic Effect of Cobalt1

…, K Miyashita, K Kamita, M Hidai

Index: Ishii; Miyashita; Kamita; Hidai Journal of the American Chemical Society, 1997 , vol. 119, # 27 p. 6448 - 6449

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Citation Number: 64

Abstract

We have long been interested in development of homogeneous heterobimetallic catalyst systems composed of two different metal complexes which might be used for unique organic synthesis. During our continuing study toward this direction, we have developed several mixed-metal catalyst systems for various types of carbonylation reactions including the homologation of methanol, 2 hydroformylation of olefins, 3 formylation of iodoarenes, 4 ...