Reductive Cleavage of the C sp 2 C sp 3 Bond of Secondary Benzyl Alcohols: Rhodium Catalysis Directed by N??Containing Groups

…, ZQ Lei, Y Li, WH Ye, LS Zhang, J Sun…

Index: Chen, Kang; Li, Hu; Lei, Zhi-Quan; Li, Yang; Ye, Wen-He; Zhang, Li-Sheng; Sun, Jian; Shi, Zhang-Jie Angewandte Chemie - International Edition, 2012 , vol. 51, # 39 p. 9851 - 9855

Full Text: HTML

Citation Number: 27

Abstract

Oxidative coupling of two nucleophiles to construct a CÀC bond (Scheme1) is gradually becoming a prestigious and powerful method relative to the traditional cross-coupling reactions.[1] Specifically, recent developments in cross-dehydrogenative coupling/arylation made such a transformation more popular and “greener” and produces valuable compounds by avoiding the preactivation of easily available and inexpensive chemicals.[2] In contrast, ...

~73%

~95%

~48%

~64%

~72%

~79%

~80%

~75%

~90%

Detail

Detail

Reversible Intramolecular C− C Bond Formation/Breaking and C...

[Rao, Ying-Li; Amarne, Hazem; Zhao, Shu-Bin; McCormick, Theresa M.; Martic, Sanela; et al. Journal of the American Chemical Society, 2008 , vol. 130, p. 12898 - 12900]

Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Li...

[Arnold, Polly L.; Sanford, Melanie S.; Pearson, Stephen M. Journal of the American Chemical Society, 2009 , vol. 131, # 39 p. 13912 - 13913]

Functionalizations of Aryl C H Bonds in 2??Arylpyridines vi...

[Niu, Liting; Yang, Haijun; Yang, Daoshan; Fu, Hua Advanced Synthesis and Catalysis, 2012 , vol. 354, # 11-12 p. 2211 - 2217]