Fe (PyTACN)-catalyzed cis-dihydroxylation of olefins with hydrogen peroxide

…, K Junge, X Ribas Salamaña, M Beller…

Index: Prat, Irene; Font, David; Company, Anna; Junge, Kathrin; Ribas, Xavi; Beller, Matthias; Costas, Miquel Advanced Synthesis and Catalysis, 2013 , vol. 355, # 5 p. 947 - 956

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Abstract

Resum A family of iron complexes with general formula [Fe (II)(R, Y, XPyTACN)(CF3SO3) 2], where R, Y, XPyTACN= 1-[2′-(4-Y-6-X-pyridyl) methyl]-4, 7-dialkyl-1, 4, 7- triazacyclononane, X and Y refer to the groups at positions 4 and 6 of the pyridine, respectively, and R refers to the alkyl substitution at N-4 and N-7 of the triazacyclononane ring,...[+]