Salophan complexes of group IV metals

S Groysman, E Sergeeva, I Goldberg…

Index: Groysman, Stanislav; Sergeeva, Ekaterina; Goldberg, Israel; Kol, Moshe European Journal of Inorganic Chemistry, 2005 , # 12 p. 2480 - 2485

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Citation Number: 30

Abstract

Abstract The coordination chemistry of tetradentate Salophan ligands with titanium and zirconium alkoxides is described for the first time. Three new Salophan ligand precursors featuring different phenolate substituents (ortho-Me, ortho, para-di-Cl, ortho, para-di-tBu) were synthesized in addition to the known prototypical Salophan precursor, by a sequence of condensation and reduction. All ligand precursors were reacted with the metal ...