e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Tetrahedron letters
Stereoselective acyl transfer reactions controlled by the diphenylphosphinoyl group: X-ray structures of stable crystalline silylated tetrahedral intermediates
N Feeder, G Hutton, S Warren
Index: Feeder, Neil; Hutton, Gordon; Warren, Stuart Tetrahedron Letters, 1994 , vol. 35, # 32 p. 5911 - 5914
Abstract Acyl transfer with LDA on benzoates of single diastereoisomers of 3- hydroxyalkyldiphenylphosphine oxides in the presence of trimethylsilyl chloride gives silylated tetrahedral intermediates in carbonyl displacement reactions with the stereochemically controlled creation of two new chiral centres. X-rays reveal the stereochemistry.
