… O. Synthesis, Characterization, X-ray Structure Determination, and Density Functional Study of the First Stable Bis-η 1-ketenyl Complex, trans-[PtCl2 {η 1-C (PPh3) CO …

…, M Casarin, P Ganis, C Maccato, L Pandolfo…

Index: Pandolfo, Luciano; Paiaro, Gastone Gazzetta Chimica Italiana, 1990 , vol. 120, # 1 p. 53 - 56

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Citation Number: 19

Abstract

The first stable and completely characterized bis-η1-ketenyl derivative, 6, has been obtained from Zeise's salt through two consecutive substitution reactions, in which Cl-and C2H4 are replaced by ketenylidenetriphenylphosphorane, Ph3PC CO, 1. Spectroscopic and structural