Cyanophosphine Derivatives: Nitrile or Cyanide Functionality?

A Maraval, A Igau, C Lepetit, A Chrostowska…

Index: Cowley, Alan H.; Kilduff, Jan E.; Norman, Nicholas C.; Pakulski, Marek Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1986 , p. 1801 - 1808

Full Text: HTML

Citation Number: 7

Abstract

... Scheme 1. Reactivity of R−PCl 2 (2a−e) with Schwartz's Reagent [Cp 2 Zr(H)Cl] n (1 ... In marked contrast with R−PCl 2 (2a−c) the corresponding dicyanophosphine compounds R−P(CN) 2 (4a−c) were reacted with 1 equiv of Schwartz's reagent 1 in toluene to give, after ...