Biomimetic simazine oxidation catalyzed by metalloporphyrins

…, V Palaretti, AL De Faria, EJ Crevelin…

Index: Santos, Joicy Santamalvina Dos; Palaretti, Vinicius; Faria, Andre Luiz De; Crevelin, Eduardo Jose; Moraes, Luiz Alberto Beraldo De; Assis, Marilda Das Dores Applied Catalysis A: General, 2011 , vol. 408, # 1-2 p. 163 - 170

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Citation Number: 8

Abstract

The metalloporphyrin-mediated simazine oxidation was investigated, in order to evaluate whether metalloporphyrins were good biomimetic models for the oxidation of this herbicide. The commercially available second-generation metalloporphyrins: 5, 10, 15, 20-tetrakis (2, 6- dichlorophenyl) porphyrin metal (III) chloride,[M (TDCPP)] Cl; 5, 10, 15, 20-tetrakis (pentafluorophenyl) porphyrin metal (III) chloride,[M (TFPP)] Cl; and 5, 10, 15, 20-tetrakis ( ...