One-pot synthesis of vinyl phosphonates from 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid

SR Sheng, WK Sun, MG Hu, XL Liu…

Index: Sheng, Shou-Ri; Sun, Wu-Kang; Hu, Ming-Gang; Liu, Xiao-Ling; Wang, Qiu-Ying Journal of Chemical Research, 2007 , # 2 p. 97 - 99

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Abstract

Vinyl phosphonates were prepared with good yields in a one-pot, two-step transformation by Mitsunobu reaction of 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid followed by oxidation-elimination. ... Keywords: 2-hydroxyalkyl phenyl selenide, monoethyl esters of phosphonic acid, Mitsunobu condition, vinyl phosphonate, oxidation-elimination ... * Correspondent. E-mail: shengsr@jxnu.edu.cn ... Organophosphonates are an important ...