P 2 O 5 /SiO 2 (30% w/w) was applied as an efficient, heterogeneous, and reusable catalyst for the synthesis of β-enaminones. The reactions were rapidly completed at 80 °C under solvent-free conditions and products were obtained in good to excellent yields. ... P 2 O 5 /SiO 2 (30% w/w) was applied as an efficient, heterogeneous, and reusable catalyst for the synthesis of β-enaminones. The reactions were rapidly completed at 80 °C under solvent-free ...