Journal of Organometallic Chemistry

Gold versus silver-catalyzed amination of allylic alcohols

X Giner, P Trillo, C Nájera

Index: Giner, Xavier; Trillo, Paz; Najera, Carmen Journal of Organometallic Chemistry, 2011 , vol. 696, # 1 p. 357 - 361

Full Text: HTML

Citation Number: 14

Abstract

Direct substitution of the hydroxy group in allylic alcohols by different nitrogenated nucleophiles is performed using low loadings of cationic gold (I) or silver salts as catalysts. Sulfonamides, carbamates and aromatic amines can be used as nucleophiles. Comparative studies between the best catalysts, cationic (triphenylphosphite) gold (I) complex and silver triflate, demonstrate that the former catalyst shows, in general, better performance than ...

Synthesis of Azaheterocyclic Vinylphosphonates by Ring??Clos...

[Garzon, Cecile; Attolini, Mireille; Maffei, Michel European Journal of Organic Chemistry, 2013 , # 18 p. 3653 - 3657]

Convergent stereocontrol in peterson olefinations. Applicati...

[Lorne, Robert; Julia, Sylvestre A. Bulletin de la Societe Chimique de France, 1986 , # 2 p. 317 - 324]

Palladium (II)??Catalyzed Oxidative Cyclization of Allylic T...

[Joosten, Antoine; Persson, Andreas K. A.; Millet, Renaud; Johnson, Magnus T.; Baeckvall, Jan-E. Chemistry - A European Journal, 2012 , vol. 18, # 47 p. 15151 - 15157]

Reactions of n-sulfinyl-p-toluenesulfonamide with alcohols

[McFarland, John W.; Schut, Dirk; Zwanenburg, Binne Tetrahedron, 1981 , vol. 37, p. 389 - 393]