Cortical Steroid Analogs. V. Synthesis of gem-Dialkyldihydroxyacetones and 3-Butyl-3, 6-dihydroxy-1-aroyloxy-2-heptanone1a

GW Stacy, MS Khan, H Moe, CR Bresson…

Index: Stacy,G.W. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 1757 - 1761

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Abstract

By utilization of the now available gem-dialkylacetylcarbinols (111), synthesis of three gem- dialkyldihydroxyacetones (I) has been accomplished. One of these (Id) possesses the corticosteroid carbon content of 21 carbon atoms. In a different but related phase of ...