Syntheses and Crystal Structures of Two Cobalt Carboxylate− Phosphonates with 4, 4′??Bipyridine as a Secondary Metal Linker

JL Song, AV Prosvirin, HH Zhao…

Index: Song, Jun-Ling; Prosvirin, Andrey V.; Zhao, Han-Hua; Mao, Jiang-Gao European Journal of Inorganic Chemistry, 2004 , # 18 p. 3706 - 3711

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Citation Number: 22

Abstract

Abstract The hydrothermal syntheses and crystal structures of two novel cobalt carboxylate− phosphonates with 4, 4′-bipyridine (4, 4′-bipy) as the secondary metal linker are reported. Compound 1,[Co 3 (H 2 L) 2 (H 2 O) 4 (4, 4′-bipy)], where H 5 L= 4-HO 2 CC 6 H 4 CH 2 N (CH 2 PO 3 H 2) 2, crystallizes in the monoclinic space group C2/c with a= 25.9281 (5), b= 9.76310 (10), c= 17.3671 (5) Å, β= 103.290 (2), V= 4278.6 (2) Å 3, and Z= ...