Journal of the American Chemical Society

Aromatic substitution. XXXVI. Aluminum trichloride and antimony pentafluoride catalyzed Friedel-Crafts alkylation of benzene and toluene with esters and haloesters

GA Olah, J Nishimura

Index: Olah,G.A.; Nishimura,J. Journal of the American Chemical Society, 1974 , vol. 96, p. 2214 - 2220 View citing articles Show Details Binkley; Degering Journal of the American Chemical Society, 1938 , vol. 60, p. 2810 View citing articles Show Details Barkenbus; Owen Journal of the American Chemical Society, 1934 , vol. 56, p. 1206 Show Details Levaillant Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1933 , vol. 197, p. 335 Annales de Chimie (Cachan, France), 1936 , vol. <11>6, p. 495

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Citation Number: 26

Abstract

Abstract: The AlCl, or SbF6 catalyzed alkylation of benzene and toluene with alkyl chlorosulfites, arenesulfinates, chloro-and fluorosulfates, arenesulfonates, triflates, pentafluorobenzenesulfonates, and trifluoroacetates as alkylating agents was investigated in nitromethane, methylene chloride, carbon disulfide, l, 1, 2-trichlorotrifluoro-methane, or excess aromatics solution. The inter-and intramolecular selectivities of the alkylations was ...