Convenient synthesis of arylazo derivatives of quinoxaline, 1, 4??benzothiazine, and 1, 4??benzoxazine

C Párkányi, AO Abdelhamid…

Index: Parkanyi, Cyril; Abdelhamid, Abdou O.; Shawali, Ahmad S. Journal of Heterocyclic Chemistry, 1984 , vol. 21, p. 521 - 524

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Citation Number: 19

Abstract

Abstract Arylazo derivatives of quinoxaline (1, 4-benzodiazine), 1, 4-benzothiazine, and 1, 4- benzoxazine have been prepared by condensation of hydrazidoyl halides with o- phenylenediamine, o-aminothiophenol, and o-aminophenol, respectively (Table I). This method seems to be more general than the approach using coupling of reactive diazonium salts with, eg., 277–1, 4-benzothiazine. Both the spectral data and the results of HMO ...