The Mechanism of Dye Formation in Color Photography. VII. Intermediate Bases in the Deamination of Quinonediimines1

LKJ Tong, MC Glesmann, RL Bent

Index: Tong,L.K.J. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 1988 - 1996

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Citation Number: 36

Abstract

In the cases reported earlier, the rate of this reaction was a linear function of the OH- concentration. Certain amines containing hydroxyalkyl substituents on the tertiary nitrogen, however, follow a more complicated rate law. The analysis of this rate law has led to a more detailed understanding of the SN~ deamination reaction and is reported in the present paper. As before, the reaction rates are measured by determination of the yields at various ...