Tetrahedron Letters

cis-disulfides protelectron spectrum of a 6, 7-dithiabicyclo [3.2. 1] octane

FS Jørgensen, PH McCabe

Index: Jorgensen, Flemming S.; McCabe, Peter H. Tetrahedron Letters, 1983 , vol. 24, # 3 p. 319 - 322

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Citation Number: 3

Abstract

The photoelectron spectrum of 2,4-dichloro-6,7-dithiabicyclo[3.2.1]octane ( ) shows the largest sulfur lone pair energy gap ever observed as a consequence of the cis-disulfide conformation, which has been further studied by molecular mechanics (MMl) and molecular orbital (CNDO/S) calculations of the parent compound, 6,7-dithiabicyclo[3.2.1]octane ( ). ... The β SS ≈ −2.1 eV is the fact identical to the value derived by extra-polation (ref. 8), although it ...