Abstract A highly regioselective hydroaminomethylation of terminal olefins catalyzed by Rh complexes with 2, 2′, 6, 6′-tetrakis ((diphenylphosphino) methyl)-1, 1′-biphenyl (Tetrabi) ligand has been developed. Up to 99% amine selectivity, 168 linear/branched amine product ratio (n/i), and 97.4% linear amine yield has been obtained at a substrate/rhodium precursor ratio (S/Rh) of 1000 with this methodology. The turnover number was achieved ...
[Ahmed, Moballigh; Bronger, Raymond P. J.; Jackstell, Ralf; Kamer, Paul C. J.; Van Leeuwen, Piet W. N. M.; Beller, Matthias Chemistry - A European Journal, 2006 , vol. 12, # 35 p. 8979 - 8988]
