New uses for the Burgess reagent in chemical synthesis: Methods for the facile and stereoselective formation of sulfamidates, glycosylamines, and sulfamides

…, DA Longbottom, AZ Nalbandian…

Index: Nicolaou; Snyder, Scott A.; Longbottom, Deborah A.; Nalbandian, Annie Z.; Huang, Xianhai Chemistry - A European Journal, 2004 , vol. 10, # 22 p. 5581 - 5606

Full Text: HTML

Citation Number: 79

Abstract

Abstract Although the Burgess reagent (methoxycarbonylsulfamoyltriethylammonium hydroxide, inner salt) has found significant use in chemical synthesis as a dehydrating agent, almost no work has been directed towards its potential in other synthetic applications. As this article will detail, we have found that the Burgess reagent is remarkably effective at accomplishing a number of non-dehydrative synthetic tasks when applied to appropriate ...