Tetrahedron Letters

[2, 3] Sigmatropic rearrangement of S-(3-chloroallyl) thiocarbamate sulfoxides followed by a 1, 2-elimination reaction yielding unsaturated aldehydes and acid …

I Schuphan, JE Casida

Index: Schuphan,I.; Casida,J.E. Tetrahedron Letters, 1979 , # 10 p. 841 - 844

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Citation Number: 12

Abstract

No. 10 843 evident from the time-dependent buildup of an aldehyde proton signal at 6 9.46 along with formation of a double doublet at 6 6.43 and 6.59. Decomposition of2i. s conveniently monitored by the formation of a double doublet at 6 6.44 and 6.92. IR15, CI-kP and independent synthesis