Australian Journal of Chemistry

Micellar catalysis of anilide hydrolysis

TJ Broxton, LW Deady, NW Duddy

Index: Broxton,T.J. et al. Australian Journal of Chemistry, 1978 , vol. 31, p. 1525 - 1532

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Citation Number: 10

Abstract

Abstract The rate of hydrolysis of several anilides is catalysed by cationic micelles ( cetyltrimethylammonium bromide), and inhibited by anionic micelles (sodium lauryl sulfate). The magnitude of catalysis is greatest for those anilides which contain the most hydrophobic R groups (R= C 7 H 15 and Ph) and is less for those containing less hydrophobic R groups (R= Me). The magnitude of catalysis is greater for compounds activated by nitro groups ...