Israel Journal of Chemistry

Enzyme–Analogue Built Polymers. IX. Polymers with Mercapto Groups of Definite Cooperativity

G Wulff, I Schulze

Index: Wulff,G.; Schulze,I. Israel Journal of Chemistry, 1978 , vol. 17, p. 291 - 297

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Citation Number: 28

Abstract

Abstract By copolymerization of bis (p-vinylbenzyl) disulfide (1) with crosslinking monomers and subsequent reduction of the disulfide bond with diborane, polymers with two closely positioned mercapto groups were prepared. Under comparable conditions polymers with randomly distributed mercapto groups were obtained from (p-vinylbenzyl) thioacetate (2). The degree of cooperativity of the mercapto groups in polymers of (1) as well as the ...