Journal of Organometallic Chemistry

Les équilibres de rédistribution dans les dérives fluorés des éléments du IV eme Groupe: II. Affinité relative du fluor et des substituants Cl, Br, H, OCH3, N (CH3) 2 et …

SC Pace, JC Elkaïm, JG Riess

Index: Pace,S.C. et al. Journal of Organometallic Chemistry, 1973 , vol. 56, p. 141 - 157

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Citation Number: 8

Abstract

Abstract A set of constants, which describe the exchange equilibria of fluorine with a substituent Z, where Z= Br, H, OCH 3, N (CH 3) 2 and SCH 3, between the variously alkylated silicon-based central moieties of the series (CH 3) n Si, with n= 1—, are predicted on the basis of previously published data. Their values correspond to significant variations in the Si F vs. Si Z bond energies as a function of n. The validity of such predictions was ...