Journal of Physical Chemistry

Mass-selected two-color multiphoton ionization of the hydrogen-bonded complex phenol-trimethylamine: generation of the protonated ion trimethylammonium (1+)

N Mikami, I Suzuki, A Okabe

Index: Mikami, Naohiko; Suzuki, Itaru; Okabe, Akihiro Journal of Physical Chemistry, 1987 , vol. 91, # 20 p. 5242 - 5247

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Citation Number: 30

Abstract

Photoionization and photodissociation of the hydrogen-bonded 1: 1 complex of C6H50H with N (CHJ3, prepared in a supersonic expansion, have been studied by mass-selected photoionization spectroscopy using the two-color multiphoton ionization technique. The complex was initially excited to its S, state and subsequently ionized to its cation by changing the photon energy for the photoionization. A large reduction (ca. 2 eV) of the ...