Journal of Organometallic Chemistry

Le complexe [{PtCl2 (triméthyl-2, 4, 6-pyridine)} 2] catalyseur homogene d'hydrogenation et d'hydrosilylation d'olefines et d'aldehydes et cetones α, β-insatures

R Rumin

Index: Rumin, R. Journal of Organometallic Chemistry, 1983 , vol. 247, # 3 p. 351 - 356

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Citation Number: 16

Abstract

Abstract The chloro-bridged platinum (II) complex dichlorobis (2, 4, 6-trimethylpyridine)- platinum was found to be an active catalyst for homogeneous hydrogenation and hydrosilylation of olefins and α, β-unsaturated aldehydes and ketones at room temperature and under atmospheric pressure. Hydrosilylation of terminal olefins can be achieved with dimethylphenylsilane and a catalyst/reactant ratio of 10− 6/1. This complex is the first ...