Peculiarities of the behavior of succinyl dichloride in Friedel-Crafts reaction with thiophenes

VI Smirnov, AV Afanas'ev, LI Belen'kii

Index: Smirnov; Afanas'Ev; Belen'kii Chemistry of Heterocyclic Compounds, 2011 , vol. 46, # 10 p. 1199 - 1207

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Citation Number: 3

Abstract

The reactions of thiophene, 2-methyl-, and 2-bromothiophene with succinyl dichloride in the presence of AlCl 3, TiCl 4, and SnCl 4 have been studied. The effect of the acylation conditions, the relative amounts and nature of the Lewis acid on the ratio and yields of the 1,