Tetrathiafulvalene porphyrins

…, VM Lynch, JL Sessler, JO Jeppesen

Index: Nielsen, Kent A.; Levillain, Eric; Lynch, Vincent M.; Sessler, Jonathan L.; Jeppesen, Jan O. Chemistry - A European Journal, 2009 , vol. 15, # 2 p. 506 - 516

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Citation Number: 32

Abstract

Abstract Four tetrathiafulvalene (TTF)-annulated porphyrins 1–4 were synthesized and characterized. All contain a tetraphenylporphyrin (TPP) core onto which four, two, or one TTF subunits were annulated. Absorption and fluorescence spectroscopic studies together with electrochemical investigations reveal that interactions between the porphyrin system and the annulated TTF units take place in solution. The annulation of one or more TTF units to the ...